20–22 May 2014
Schloss Böttstein
Europe/Zurich timezone
AnXAS 2014

Speciation of reduced U(IV) in contaminated sediments and laboratory reactors

21 May 2014, 10:55
25m
Festsaal - Plenum (Schloss Böttstein)

Festsaal - Plenum

Schloss Böttstein

Schlossweg 20, 5315 Böttstein, Switzerland, http://www.schlossboettstein.ch
Oral Actinides in Environmental and Life Sciences Actinides in Environmental and Life Sciences

Speaker

Dr Maxim Boyanov (Argonne National Laboratory)

Description

In situ groundwater remediation or waste storage strategies often have the goal of limiting the mobility of a contaminant by decreasing its solubility in the passing aqueous phase. The chemical or enzymatic reduction of U(VI) to U(IV) presents an approach to achieve this goal by exploiting the lower solubility of uraninite (UO2) relative to that of U(VI) species. This property of U has led to extensive research aimed at understanding the mechanism of U(VI) reduction and the stability of uraninite. However, recent evidence from U LIII-edge x-ray absorption spectroscopy suggests that uraninite may not be the predominant form of U(IV) in reduced sediments on the time scale of remediation activities. We will present an example from contaminated sediments at the Oak Ridge Integrated Field Research Center,1 followed up by several laboratory studies where we find that factors such as the mechanism of enzymatic U(VI) reduction,2 groundwater components such as phosphate or carbonate,2 and the ratio of U to specific mineral surface sites,3 can prevent the precipitation of uraninite and result in the formation of complexed or adsorbed U(IV) species. The spectroscopic features allowing the identification of these species from XANES and EXAFS measurements will be highlighted. The predominance of non-uraninite U(IV) species in reduced sediments presents new analytical and transport modelling challenges that will need to be addressed in future research. 1.“In situ Bioremediation of Uranium with Emulsified Vegetable Oil as the Electron Donor”, D. B. Watson, W-M. Wu, T. Mehlhorn, G. Tang, J. Earles, K. Lowe, T. M. Gihring, G. Zhang, F. Zhang, J. Phillips, M. Boyanov, B. Spalding, C. Schadt, K. M. Kemner, C. S. Criddle, P. M. Jardine, S. C. Brooks, Environ. Sci. Technol., Environ. Sci. Technol., 47 (12), 6440–6448 (2013) 2.“Solution and Microbial Controls on the Formation of Reduced U(IV) Species”, M. Boyanov, K. Fletcher, M.-J. Kwon, X. Rui, E. O’Loughlin, F. Löffler., K. Kemner. Environ. Sci. Technol. 45, 8336-8344 (2011) 3.“Stable U(IV) complexes form at high-affinity mineral surface sites”, D. E. Latta, B. Mishra, R.E. Cook, K. M. Kemner, M. I. Boyanov, Environ.Sci.Tech., 48 (3), 1683–1691 (2014)

Primary author

Dr Maxim Boyanov (Argonne National Laboratory)

Co-authors

Dr Bhoopesh Mishra (Illinois Institute of Technology) Dr Drew Latta (University of Iowa) Dr Edward O'Loughlin (Argonne National Laboratory) Dr Ken Kemner (Argonne National Laboratory)

Presentation materials

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