Operando VII

Europe/Zurich
Sunstar Hotel (Grindelwald)

Sunstar Hotel

Grindelwald

Dorfstrasse 168, 3818 Grindelwald Switzerland
Davide Ferri (Paul Scherrer Institut), Maarten Nachtegaal (Paul Scherrer Institut)
Description

Welcome to the webpage of Operando VII - the 7th International Congress on Operando Spectroscopy.


NEWS

A big thank you to all participants and sponsors for a fantastic Operando VII congress!!!

Now you can submit a manuscript to Catalysis Today for inclusion in the special issue on Operando VII


The main objective of this congress is to bring researchers together to discuss the progress of operando methodologies, i.e. characterization of functional materials in their working state. In operando studies, physicochemical methods probe the behavior of working materials while their performance is measured simultaneously. The operando approach is suited to elucidate catalyst structure-activity relationships at the molecular level.

Both academia and industry recognize the importance of this approach that is now a well-established research area in catalysis.


This event followed the congress series of 2003 (Lunteren, The Netherlands), 2006 (Toledo, Spain), 2009 (Rostock, Germany), 2012 (Brookhaven National Laboratory, USA), 2015 (Deauville, France) and 2018 (Estepona, Spain).


Our sponsors

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Organizing institution   
   

 

    • 10:00 AM 6:00 PM
      Registration
    • 12:00 PM 1:50 PM
      Lunch 1h 50m
    • 1:50 PM 2:00 PM
      Welcome
    • 2:00 PM 2:30 PM
      Keynote lecture: Design of XAS experiments for uncovering active sites in heterogeneous catalysts
      Convener: Olga Safonova (Paul Scherrer Institut, Villigen PSI, Switzerland)
    • 2:30 PM 2:50 PM
      Contributed presentations: Operando XAS at high pressure: the case of direct synthesis of hydrogen peroxide
      Convener: Dmitry Doronkin (Karlsruhe Institute of Technology)
    • 2:50 PM 3:10 PM
      Contributed presentations: The NO-N2O-SCR reaction: a catalytic and spectroscopic investigation
      Convener: Filippo Buttignol (PSI - Paul Scherrer Institut)
    • 3:10 PM 3:40 PM
      Coffee 30m
    • 3:40 PM 4:00 PM
      Contributed presentations: Identifying the active sites and their kinetics for butadiene synthesis from ethanol for ZnO/SiO2, ZrO2/SiO2, and ZnO-ZrO2/SiO2 Catalysts by modulation excitation infrared spectroscopy
      Convener: Israel Wachs
    • 4:00 PM 4:20 PM
      Contributed presentations: Chasing adorbates and metal particle state for ceria supported Rh and Pt during CO2 methanation and CO oxidation conditions
      Convener: Per-Anders Carlsson (Chalmers University of Technology)
    • 4:20 PM 4:40 PM
      Contributed presentations: Genesis of active Pt/CeO2 catalyst for dry reforming of methane by reduction and aggregation of isolated Platinum atoms into clusters
      Convener: Simon Bare (Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory)
    • 4:40 PM 5:00 PM
      Contributed presentations: Operando FTIR study of the understanding reactional mechanisms of the decomposition of N2O under real industrial conditions
      Convener: Mathias Laluc
    • 5:00 PM 5:20 PM
      Contributed presentations: Mechanistic studies of continuous glucose upgrading over Lewis acidic silicates by operando UV−Vis and HSQC NMR
      Convener: Ceri Hammond (Imperial College London)
    • 6:50 PM 7:00 PM
      Opening ceremony
    • 7:00 PM 8:00 PM
      Opening lecture: In situ Mössbauer spectroscopy on Mars
      Convener: Franz Renz (Leibniz University Hanover)
    • 8:00 PM 9:30 PM
      Welcome dinner 1h 30m
    • 9:00 AM 10:00 AM
      Plenary lecture: Materials for clean air, selective oxidation and sustainable chemicals: Probing catalysts at various complexity scales by operando spectroscopy and microscopy
      Convener: Jan-Dierk Grunwaldt (KIT)
    • 10:00 AM 10:20 AM
      Contributed presentations: Operando characterization of Fischer-Tropsch synthesis products in a fixed-bed reactor by magnetic resonance
      Convener: Qingyuan Zheng (Department of Chemical Engineering and Biotechnology, University of Cambridge)
    • 10:20 AM 10:40 AM
      Contributed presentations: Oxidation of Hägg carbide during high temperature Fischer-Tropsch synthesis: Size-dependent thermodynamics and in-situ observations
      Convener: Michael Claeys (University of Cape Town)
    • 10:40 AM 11:10 AM
      Coffee 30m
    • 11:10 AM 11:30 AM
      Contributed presentations: Operando XAS-tomography reveals chemical gradients in Pt/Al2O3 and Cu-SSZ-13 emissions control catalysts
      Convener: Srashtasrita Das (Karlsruhe Institute of Technology)
    • 11:30 AM 11:50 AM
      Contributed presentations: Spatiotemporal operando methodologies on the reactor scale for mechanistic and kinetic studies
      Convener: Atsushi Urakawa (Delft University of Technology)
    • 11:50 AM 12:10 PM
      Contributed presentations: Insights on Rh and Pt nanoparticle dynamics by operando XAS spectroscopy during CO2 activation via reverse water gas shift
      Convener: Chiara Negri (Laboratory of Catalysis and Catalytic Processes, Department of Energy, Politecnico di Milano)
    • 12:10 PM 1:30 PM
      Lunch 1h 20m
    • 1:30 PM 2:00 PM
      Keynote lecture: In situ and operando spectroscopic study for multi-elemental reverse water-gas shift catalysts identified using extrapolative machine learning approach
      Convener: Takashi Toyao (Institute of Catalysis, Hokkaido university)
    • 2:00 PM 2:20 PM
      Contributed presentations: Dynamic evolution of Pd single atoms on anatase TiO2 under RWGS reaction conditions
      Convener: Janos Szanyi (Pacific Northwest National Laboratory)
    • 2:20 PM 2:40 PM
      Contributed presentations: Mechanistic insights into reverse water gas shift reaction over Au supported catalysts by operando spectroscopic techniques
      Convener: Abdallah ahmed (Leibniz-Institut für Katalyse, Albert-Einstein-Str. 29 A, 18059 Rostock, Germany)
    • 2:40 PM 3:00 PM
      Contributed presentations: Assessing the structure of SiO2-supported Ni-Ga nanoparticles under CO2 hydrogenation to methanol conditions via in-situ X-ray absorption, total scattering and infrared experiments
      Convener: Nora Zimmerli (ETH Zürich)
    • 3:00 PM 3:20 PM
      Contributed presentations: A UV-Vis/ATR-IR operando spectroscopy approach to study photo-active metal-organic frameworks
      Convener: Bettina Baumgartner (Utrecht University)
    • 3:20 PM 3:40 PM
      Contributed presentations: In situ monitoring by X-ray absorption spectroscopy of the synthesis and catalytic behavior of carbon-supported Pt single-atom catalysts in acetylene hydrochlorination
      Convener: Vera Giulimondi (ETH Zurich)
    • 3:40 PM 4:10 PM
      Coffee 30m
    • 4:10 PM 4:40 PM
      Keynote lecture: Restructuring of titanium oxide overlayers over nickel nanoparticles during catalysis as probed with operando electron microscopy and infrared spectroscopy
      Convener: Matteo Monai (Utrecht University)
    • 4:40 PM 5:00 PM
      Contributed presentations: Understanding the structural evolution of the most active PdZn nanoparticles used for CO2 activation
      Convener: Sofia Mediavilla Madrigal
    • 5:00 PM 5:20 PM
      Contributed presentations: Quantitative transient IR analyses of CO2 hydrogenation to methanol over Cu/ZrO2 reveal Cu-bound formates as main reaction intermediates
      Convener: Frédéric Meunier (CNRS IRCELYON)
    • 5:20 PM 5:40 PM
      Contributed presentations: Catalysis operando studies combined with computed X-ray diffraction tomography: Coke formation during conversion of Methanol to Gasoline
      Convener: Lars Lundegaard (Topsoe)
    • 5:40 PM 7:30 PM
      Poster session
    • 7:30 PM 9:00 PM
      Swiss dinner
    • 9:00 AM 9:30 AM
      Keynote lecture: Steps towards understanding the oxygen evolution reaction enigma by operando quick X-ray absorption spectroscopy
      Convener: Emiliana Fabbri (Paul Scherrer Institut)
    • 9:30 AM 9:50 AM
      Contributed presentations: Operando experiments and DFT calculations to understand the chemistry of electrocatalytic oxygen evolution
      Convener: Detre Teschner
    • 9:50 AM 10:10 AM
      Contributed presentations: Characterizing small metallic nanoparticles with operando X-ray scattering techniques during electrocatalysis
      Convener: Rebecca Pittkowski (University of Copenhagen)
    • 10:10 AM 10:30 AM
      Contributed presentations: Understanding the cycling performance of LiMn2O4 spinel nanoparticles achieved by operando XAS spectroscopy
      Convener: Juliana Bruneli Falqueto (PSI - Paul Scherrer Institut)
    • 10:30 AM 11:00 AM
      Coffee 30m
    • 11:00 AM 11:20 AM
      Contributed presentations: Modulated excitation operando FT-IR and quick-X-ray absorption spectroscopy of electrooxidation over Ni-based catalysts
      Convener: Charlotte Vogt (Technion - Israel Institute of Technology)
    • 11:20 AM 11:40 AM
      Contributed presentations: Reaction-induced restructuring in dilute alloy catalysts
      Convener: Anatoly Frenkel (Stony Brook University)
    • 11:40 AM 12:00 PM
      Contributed presentations: Transient APXPS as a tool to characterize the kinetics of alloy restructuring: application to Sn-poor PtSn ALD-derived nanoparticles
      Convener: Evgeniy Redekop (University of Oslo)
    • 12:00 PM 1:30 PM
      Lunch 1h 30m
    • 1:30 PM 5:40 PM
      Free program
    • 5:40 PM 7:00 PM
      Poster session
    • 7:00 PM 8:00 PM
      Dinner 1h
    • 8:00 PM 9:00 PM
      Discussion panel: Operando at synchrotron facilities: Quo Vadis?
    • 8:00 PM 9:00 PM
      Discussion panel: Operando cell design
    • 9:00 AM 10:00 AM
      Plenary lecture: Operando, multimodal characterization of bimetallic catalysts with electrons and x-rays
      Convener: Eric Stach (University of Pennsylvania)
    • 10:00 AM 10:20 AM
      Contributed presentations: Self-sustained oscillatory dynamics of ethylene to syngas by operando SEM and XPS
      Convener: Claudiu Colbea (ETH Zurich)
    • 10:20 AM 10:40 AM
      Contributed presentations: 3D strain dynamics during CO oxidation revealed by Bragg-CDI
      Convener: Amélie Rochet (CNPEM - Sirius)
    • 10:40 AM 11:10 AM
      Coffee 30m
    • 11:10 AM 11:30 AM
      Contributed presentations: Spatiotemporal operando UV-Vis spectroscopy on the reactor scale
      Convener: Louise van Beek
    • 11:30 AM 11:50 AM
      Contributed presentations: Site-dependent analysis of sulfur poisoning impact on H2 dissociation and sorption on Pd nanoparticles with operando IR nano-spectroscopy
      Convener: Elad Gross (Hebrew University)
    • 11:50 AM 12:10 PM
      Contributed presentations: Operando spectroscopies and olefin polymerization catalysis: a rare marriage with a lot of unexplored potentials
      Convener: Elena Groppo (University of Turin)
    • 12:10 PM 1:30 PM
      Lunch 1h 20m
    • 1:30 PM 2:00 PM
      Keynote lecture: Elucidating CO2 activation over reducible oxide catalysts using operando and transient spectroscopies
      Convener: Christian Hess (TU Darmstadt)
    • 2:00 PM 2:20 PM
      Contributed presentations: Catalysts for dehydroaromatization of methane: insights from operando spectroscopy
      Convener: Nikolay Kosinov
    • 2:20 PM 2:40 PM
      Contributed presentations: EPR investigation of metal oxide catalysts: carbon dioxide to methanol conversion induced by oxygen vacancies
      Convener: Mikhail Agrachev (ETH Zurich)
    • 2:40 PM 3:00 PM
      Contributed presentations: Tuning metal-support interactions in the CO2 hydrogenation over Ni/TiO2
      Convener: Angela Melcherts (Utrecht University)
    • 3:00 PM 3:20 PM
      Contributed presentations: Cu-MOFs as oxygenation catalysts: an operando XAS study
      Convener: Matteo Signorile (Università Di Torino - Dipartimento di Chimica)
    • 3:20 PM 3:40 PM
      Contributed presentations: Unravelling metal ratio-dependent synergistic effects in bimetallic CO2 hydrogenation catalysts by operando X-ray absorption and infrared spectroscopy
      Convener: Dr Nina Genz (Utrecht University)
    • 3:40 PM 4:10 PM
      Coffee 30m
    • 4:10 PM 4:40 PM
      Keynote lecture: Second and micrometer spatial resolution for operando characterizations of heterogeneous energy-related materials by Full Field Hyperspectral Quick-EXAFS Imaging
      Convener: Valérie Briois (2)
    • 4:40 PM 5:00 PM
      Contributed presentations: Operando DRIFT study of highly disperse CeO2 nanoparticles supported on MgO hexagonal plates during toluene oxidation
      Convener: Alejo Aguirre (INTEC (CONICET-UNL))
    • 5:00 PM 5:20 PM
      Contributed presentations: Attenuation of dimethyl ether formation from the reaction of methanol over an alumina-based methyl chloride synthesis catalyst
      Convener: David Lennon (University of Glasgow)
    • 5:20 PM 5:40 PM
      Contributed presentations: Localised thermal levering events drive spontaneous kinetic oscillations in catalysis
      Convener: Peter Wells
    • 5:40 PM 6:00 PM
      Closing remarks
    • 7:00 PM 9:00 PM
      Congress dinner
    • 9:00 AM 9:30 AM
      Departure to Operando School