21–25 Sept 2026
Paul Scherrer Institut
Europe/Zurich timezone

Circularly-polarized IR FEL pulses selectively probe dynamic processes and pump Rydberg states in doped semiconductors

21 Sept 2026, 16:11
1m
SwissFEL

SwissFEL

Entrance
Oral Quantum Science Poster Session (I)

Speaker

Guy Matmon (PSI - Paul Scherrer Institut)

Description

Abstract:
Short, coherent pulses from infrared free electron lasers has been used extensively for studying population dynamics, and to a lesser extent coherence, of bound carrier states in semiconductors. Here we focus specifically on the hydrogen atom-like states of single donors and acceptors. Several challenges beset characterisation: the ladder of excited bound states is closely spaced in relation to the incident beam line width, and states lie very close to the conduction or valence band continuum. Measuring basic parameters such as the population life time $T_1$ is open to different interpretations. Coherent measurements such as photon echo and Ramsey spectroscopy offer a way to disambiguate this but require more complex setups than pump-probe. We demonstrate that by using a circularly polarized pump and a linearly polarized probe at ~10 THz we can harness the inherent optical dichroism of the excited Rydberg states to correctly attribute different decay paths of excited Rydberg states in phosphorus-doped silicon using only two beams, measuring optical Faraday rotations up to ±8°.

Access to circularly polarized IR FEL pulses allows us to harness spin selection rules to demonstrate optical pumping of hole spins in boron-doped silicon, analogous to spin preparation in atomic physics. We find a single dark state in the J=3/2 manifold of the hole’s orbital ground state that is not excited by circularly polarized light, and preferentially pump holes from the other Jz eigenstates into it. We recover two time scales: a fast (~30 psec) orbital decay and a slow (~1 nsec) spin decay. The measured decay and population transfer can be modelled with a rate equation and a few simple assumptions. We propose a realistic path to 99% spin initialization within hundreds of picoseconds, several orders of magnitude faster than current microwave initialization-based protocols.

Scientific Topics Quantum Science

Authors

Dr Aidan McConnell (PSI) Alexander Balatsky (Nordita) Prof. Ben Murdin (7Advanced Technology Institute and Department of Physics, University of Surrey, Guildford, GU2 7XH, UK) Gabriel Aeppli (PSI - Paul Scherrer Institut) Guy Matmon (PSI - Paul Scherrer Institut) Dr Lorenzo Amato (PSI) Markus Müller (PSI - Paul Scherrer Institut) Dr Nikolay Abrosimov (Leibniz-Institut für Kristallzüchtung (IKZ), 12489 Berlin, Germany) Nils Deßmann (Institute for Molecules and Materials, FELIX Laboratory, Radboud University, Nijmegen, The Netherlands) Sergey Pavlov (German Aerospace Center) Mr Wojciech Adamczyk (Institute for Quantum Electronics, ETH Zurich, Zurich, CH-8093, Switzerland)

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