15–16 Sept 2011
Paul Scherrer Institut, Villigen, Switzerland
Europe/Zurich timezone

Quantitative microscopic studies with high spatial resolution: the virtue of cross-calibration

16 Sept 2011, 11:15
20m
OSGA/E6 (Paul Scherrer Institut, Villigen, Switzerland)

OSGA/E6

Paul Scherrer Institut, Villigen, Switzerland

Talk Advancing Quantitative Chemical Imaging Advancing Quantative Chemical Imaging

Speaker

Dr H A O Wang (ETH Zürich, Switzerland)

Description

Trace elements quantification is normally a difficult task in micro X-ray fluorescence analysis (microXRF), also inevitable in high flux synchrotron-based microXRF (SR-microXRF). However the high spatial resolution and high throughput of SR-microXRF are the advantages among chemical analysis techniques. In this work, we combined it with laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS), which provided quantitative output on trace elements, but in less spatial resolution. Both techniques show 2D chemical images in agreement. Therefore, we used quantitative information from LA-ICPMS to calibrate the SR-microXRF analysis, resulting in a quantitative 2D image with high spatial resolution. [1] Wang, H. A. O.; Grolimund, D.; Van Loon, L. R.; Barmettler, K.; Borca, C. N.; Aeschlimann, B.; Günther, D. Anal. Chem. 2011, accepted.

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Advancing quantitative chemical imaging

Primary author

Dr H A O Wang (ETH Zürich, Switzerland)

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